Great questions.
You can find a well-maintained, frequently updated set of the laws of all 50 states
here. The Delaware page includes a list of the places where
state law says you cannot carry.
However, you are responsible to verify the laws yourself: just because a place isn't listed on a Web site doesn't make it legal. When I have a question, I read the law itself and/or ask my lawyer*.
As for other places, IANAL ("I Am Not A Lawyer") and YMMV ("Your Mileage May Vary"), but I don't think signs at private businesses -- like the crappy little sign at a local movie theater or the "Code of Conduct" at a local shopping mall -- have force of law. My lawyer* agrees: he advises me to leave voluntarily and politely if asked, and assures me that I am unlikely to face criminal prosecution if I
ignore fail to notice the signs.
(The "DO NOT ENTER WITH A LOADED GUN" sign at Miller's Guns has, if not force of law, force of arms behind it, so I would suggest you obey that one).
*Speaking of lawyers: who are
you going to call? In other words, have you chosen your criminal defense attorney (and does he or she know you have chosen them)?
This is a decision you should make & prepare for today, not at 4AM in the Wawa parking lot.